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Methyltriphenylphosphonium bromide information


Methyltriphenylphosphonium bromide
Names
Preferred IUPAC name
Methyltri(phenyl)phosphanium bromide
Identifiers
CAS Number
  • 1779-49-3
3D model (JSmol)
  • Interactive image
ChEMBL
  • ChEMBL54469
ChemSpider
  • 67086
EC Number
  • 217-218-9
PubChem CID
  • 74505
UNII
  • LW2UZ3E9EG
CompTox Dashboard (EPA)
  • DTXSID30883580
InChI
  • InChI=1S/C19H18P.BrH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
    Key: LSEFCHWGJNHZNT-UHFFFAOYSA-M
SMILES
  • C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
Properties
Chemical formula
C19H18BrP
Molar mass 357.231 g·mol−1
Appearance white solid
Hazards
GHS labelling:
Pictograms
GHS06: ToxicGHS07: Exclamation markGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H300, H301, H302, H312, H315, H319, H332, H411
Precautionary statements
P261, P264, P270, P271, P273, P280, P301+P310, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P391, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Methyltriphenylphosphonium bromide is the organophosphorus compound with the formula [(C6H5)3PCH3]Br. It is the bromide salt of a phosphonium cation. It is a white salt that is soluble in polar organic solvents.

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Methyltriphenylphosphonium bromide

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Methyltriphenylphosphonium bromide is the organophosphorus compound with the formula [(C6H5)3PCH3]Br. It is the bromide salt of a phosphonium cation....

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Methylenetriphenylphosphorane

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basic species. Methylenetriphenylphosphorane is prepared from methyltriphenylphosphonium bromide by its deprotonation using a strong base like butyllithium:...

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Phosphonium

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example, the reaction of triphenylphosphine with methyl bromide gives methyltriphenylphosphonium bromide: PPh3 + CH3Br → [CH3PPh3]+Br− The methyl group in such...

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Organophosphine

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readily alkylated. For example, methyl bromide converts triphenylphosphine to the methyltriphenylphosphonium bromide, a "quat salt": PPh3 + CH3Br → [CH3PPh3+]Br−...

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Bromoantimonates

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compounds containing anions composed of bromide (Br−) and antimony (Sb). They can be considered as double bromides, metallohalides or halometallates. They...

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