Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Methylenecyclopropane is an organic compound with the formula (CH2)2C=CH2. It is a hydrocarbon which, as the name suggests, is derived from the addition of a methylene (=CH2) substituent to a cyclopropane ring. It is a colourless, easily condensed gas that is used as a reagent in organic synthesis.
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Methylenecyclopropane is an organic compound with the formula (CH2)2C=CH2. It is a hydrocarbon which, as the name suggests, is derived from the addition...
precursor to methallyl ligand. It is an isomer of crotyl chloride. Methylenecyclopropane can be synthesised via an intramolecular cyclisation reaction from...
Dimethylacetylene (2-butyne) 1-Methylcyclopropene 3-Methylcyclopropene Methylenecyclopropane Trimethylenemethane 1-butyne This set index page lists chemical...
eliminated, cyclic compounds may be formed, as in the preparation of methylenecyclopropane below. Cyclopropenes, aziridines and cyclobutanes may be formed...
certain reactions is also reported in conjunction with the use of methylenecyclopropane groups as protective groups for amines.[citation needed] Lide, David...
with a methylene (methylidine) group attached. Methylcyclohexane Methylenecyclopropane Wittig, George; Schoellkopf, U. (1960). "Methylenecyclohexane"....
oxaspiropentane, which is formed by epoxidation of the easily accessible methylenecyclopropane: Cyclobutanone can also be prepared in a two step procedure by dialkylation...
rings that share a single central carbon-carbon bond. Cyclopropene Methylenecyclopropane Merck Index, 11th Edition, 2755. "Front Matter". Nomenclature of...
electron-accepting groups bonded to the methylidene carbon atom. Methylenecyclopropane Cyclopropene Cyclopropane Fulvene Cyclopropenone Methylene group...
(2003). "Synthesis and [3+2] Cycloaddition of a 2,2-Dialkoxy-1-methylenecyclopropane: 6,6-Dimethyl-1-methylene-4,8-Dioxaspiro[2.5]octane and cis-5-(5...
In the presence of [Fe2(CO)9], the ring opening of 2-substituted methylenecyclopropanes leads to the formation of various η4-trimethylenemethane complexes...
with Fe(C 4H 6)(CO)3, which was obtained by the ring-opening of methylenecyclopropane with diiron nonacarbonyl (Fe 2(CO)9). The same complex was prepared...
Mehrisheikh-Mohammadi, M. E. (1985). "Captodative Rate Enhancement in the Methylenecyclopropane Rearrangement". Journal of Organic Chemistry. 51 (14): 2664–2668...
Tomoaki; Ogoshi, Sensuke (2010-06-14). "[3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient...
Alois; Aïssa, Christophe (2006). "PtCl-Catalyzed Rearrangement of Methylenecyclopropanes". Journal of the American Chemical Society. 128 (19): 6306–6307...
intermolecular-intramolecular cyclization of homopropargylic radicals leads to methylenecyclopropanes. The optimal conditions for TMM cycloadditions depend on both the...
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