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Magnesium perchlorate information


Magnesium perchlorate
Magnesium perchlorate
Identifiers
CAS Number
  • 10034-81-8 checkY
  • 64010-42-0 (hydrate) checkY
  • 13446-19-0 (hexahydrate) checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 23223 checkY
ECHA InfoCard 100.030.086 Edit this at Wikidata
PubChem CID
  • 24840
RTECS number
  • SC8925000
UNII
  • 7N77Z541YF ☒N
CompTox Dashboard (EPA)
  • DTXSID70890617 Edit this at Wikidata
InChI
  • InChI=1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2 checkY
    Key: MPCRDALPQLDDFX-UHFFFAOYSA-L checkY
  • InChI=1/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
    Key: MPCRDALPQLDDFX-NUQVWONBAH
SMILES
  • [Mg+2].O=Cl(=O)(=O)[O-].[O-]Cl(=O)(=O)=O
Properties
Chemical formula
Mg(ClO4)2
Molar mass 223.206 g/mol
Appearance white powder,
deliquescent
Odor odorless
Density 2.21 g/cm3 (anhydrous)
1.98 g/cm3 (hexahydrate)
Melting point 251 °C (484 °F; 524 K) (anhydrous)
95-100 °C (hexahydrate)
Boiling point decomposition
Solubility in water
99.3 g/100 mL
Solubility in ethanol 23.96 g/100 mL
Hazards[1]
Occupational safety and health (OHS/OSH):
Main hazards
Oxidizer
GHS labelling:
Pictograms
GHS03: OxidizingGHS07: Exclamation mark
Signal word
Danger
Hazard statements
H272, H315, H319, H335
Precautionary statements
P220, P261, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
1
0
0
OX
Safety data sheet (SDS) External MSDS
Related compounds
Other cations
Calcium perchlorate
Barium perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO4)2. The salt is also a superior drying agent for gas analysis.

Magnesium perchlorate decomposes at 250 °C.[2] The heat of formation is -568.90 kJ/mol.[3]

The enthalpy of solution is quite high, so reactions are done in large amounts of water to dilute it.

It is sold under the trade name anhydrone. Manufacture of this product on a semi-industrial scale was first performed by G. Frederick Smith in his garage in Urbana Illinois, but later at a permanent facility in Columbus, OH called G. Frederick Smith Chemical Co. He sold the magnesium perchlorate to A. H. Thomas Co., now Thomas Scientific, under the trade name Dehydrite.

  1. ^ "Magnesium Perchlorate, Anhydrous". American Elements. Retrieved August 28, 2019.
  2. ^ "Physical Constants of Inorganic Compounds". CRC Handbook of Chemistry and Physics (97th ed.). Taylor and Francis Group. 2016. pp. 4–72. Retrieved June 4, 2023.
  3. ^ Lange, Norbert Adolph; Dean, John Aurie (1992). "Thermodynamic properties". Lange's Handbook of Chemistry (14th ed.). McGraw-Hill. p. 6.85.

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