Lithium titanate information

Lithium titanate
	; __Li+ __ Ti4+ __ O2−
Names
	Other names Lithium metatitanate
Identifiers
CAS Number	12031-82-2 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.031.586
PubChem CID	160968;
CompTox Dashboard (EPA)	DTXSID20923323 ;
	InChI InChI=1S/2Li.3O.Ti/q2+1;3-2;+4 Key: AXQWGBXVDWYWDE-UHFFFAOYSA-N;
	SMILES [Li+].[Li+].[O-2].[O-2].[O-2].[Ti+4];
Properties
Chemical formula	Li2TiO3
Molar mass	109.76
Appearance	White powder
Density	3.43 g/cm3
Melting point	1,533 °C (2,791 °F; 1,806 K)
Structure
Crystal structure	Monoclinic, mS48, No. 15
Space group	C2/c
Lattice constant	a = 0.505 nm, b = 0.876 nm, c = 0.968 nm α = 90°°, β = 100°°, γ = 90°°
Lattice volume (V)	0.4217 nm3
Formula units (Z)	8
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Lithium titanates are chemical compounds of lithium, titanium and oxygen. They are mixed oxides and belong to the titanates. The most important lithium titanates are:

lithium titanate spinel, Li₄Ti₅O₁₂ and the related compounds up to Li₇Ti₅O₁₂. These titanates are used in lithium-titanate batteries.
lithium metatitanate, a compound with the chemical formula Li₂TiO₃ and a melting point of 1,533 °C (2,791 °F)^[4] It is a white powder with possible applications in tritium breeding materials in nuclear fusion applications.

Other lithium titanates, i.e. mixed oxides of the system Li₂O–TiO₂, are:

Lithium orthotitanate Li₄TiO₄, melting point of 1,200 °C (2,190 °F)^[4]
Ramsdellite lithium titanate Li₂Ti₃O₇ and Li_xTiO₂ (0 ≦ x ≦ 0.57) with ramsdellite structure.^[5]

^ ^a ^b Hanaor, Dorian A.H.; Kolb, Matthias H.H.; Gan, Yixiang; Kamlah, Marc; Knitter, Regina (2014). "Solution based synthesis of mixed-phase materials in the Li₂TiO₃-Li₄SiO₄ system". Journal of Nuclear Materials. 456: 151–161. arXiv:1410.7128. Bibcode:2015JNuM..456..151H. doi:10.1016/j.jnucmat.2014.09.028. S2CID 94426898.
^ Van Der Laan, J.G; Muis, R.P (1999). "Properties of lithium metatitanate pebbles produced by a wet process". Journal of Nuclear Materials. 271–272: 401–404. Bibcode:1999JNuM..271..401V. doi:10.1016/S0022-3115(98)00794-6.
^ Claverie J., Foussier C., Hagenmuller P. (1966) Bull. Soc. Chim. Fr. 244-246
^ ^a ^b Dorian Hanaor; Matthias Kolb; Yixiang Gan; Marc Kamlah; Regina Knitter (2014). "Mixed phase materials in the Li₄SiO₄ Li₂TiO₃ system". Journal of Nucl Materials. 456: 151–166.
^ Tsuyumoto, Isao; Moriguchi, Takumi (October 2015). "Synthesis and lithium insertion properties of ramsdellite LixTiO2 anode materials". Materials Research Bulletin. 70: 748–752. doi:10.1016/j.materresbull.2015.06.014.

[crc-1] Hanaor, Dorian A.H.; Kolb, Matthias H.H.; Gan, Yixiang; Kamlah, Marc; Knitter, Regina (2014). "Solution based synthesis of mixed-phase materials in the Li₂TiO₃-Li₄SiO₄ system". Journal of Nuclear Materials. 456: 151–161. arXiv:1410.7128. Bibcode:2015JNuM..456..151H. doi:10.1016/j.jnucmat.2014.09.028. S2CID 94426898.

[Laan-2] Van Der Laan, J.G; Muis, R.P (1999). "Properties of lithium metatitanate pebbles produced by a wet process". Journal of Nuclear Materials. 271–272: 401–404. Bibcode:1999JNuM..271..401V. doi:10.1016/S0022-3115(98)00794-6.

[3] Claverie J., Foussier C., Hagenmuller P. (1966) Bull. Soc. Chim. Fr. 244-246

[Knitter-4] Dorian Hanaor; Matthias Kolb; Yixiang Gan; Marc Kamlah; Regina Knitter (2014). "Mixed phase materials in the Li₄SiO₄ Li₂TiO₃ system". Journal of Nucl Materials. 456: 151–166.

[5] Tsuyumoto, Isao; Moriguchi, Takumi (October 2015). "Synthesis and lithium insertion properties of ramsdellite LixTiO2 anode materials". Materials Research Bulletin. 70: 748–752. doi:10.1016/j.materresbull.2015.06.014.

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Names

__Li⁺ __ Ti⁴⁺ __ O²⁻
Other names Lithium metatitanate
Identifiers
CAS Number	12031-82-2^Y
3D model (JSmol)	Interactive image
ECHA InfoCard	100.031.586
PubChem CID	160968
CompTox Dashboard (EPA)	DTXSID20923323
InChI InChI=1S/2Li.3O.Ti/q2+1;3-2;+4 Key: AXQWGBXVDWYWDE-UHFFFAOYSA-N
SMILES [Li+].[Li+].[O-2].[O-2].[O-2].[Ti+4]
Properties
Chemical formula	Li₂TiO₃
Molar mass	109.76
Appearance	White powder^[1]
Density	3.43 g/cm³^[2]
Melting point	1,533 °C (2,791 °F; 1,806 K)^[1]
Structure^[3]
Crystal structure	Monoclinic, mS48, No. 15
Space group	C2/c
Lattice constant	a = 0.505 nm, b = 0.876 nm, c = 0.968 nm α = 90°°, β = 100°°, γ = 90°°
Lattice volume (V)	0.4217 nm³
Formula units (Z)	8
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references