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Lithium iodate information


Lithium iodate
Skeletal formula of lithium iodate with I—O bond length
Crystal structure of lithium iodate, iodines are inside the unit cell
Names
IUPAC name
Lithium iodate
Identifiers
CAS Number
  • 13765-03-2 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 141432 checkY
ECHA InfoCard 100.033.954 Edit this at Wikidata
EC Number
  • 237-365-2
PubChem CID
  • 3084149
UNII
  • 1685PBD1HF checkY
UN number 1479
CompTox Dashboard (EPA)
  • DTXSID601014446 DTXSID30925318, DTXSID601014446 Edit this at Wikidata
InChI
  • InChI=1S/HIO3.Li/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 checkY
    Key: FZAXZVHFYFGNBX-UHFFFAOYSA-M checkY
SMILES
  • [Li+].[O-]I(=O)=O
Properties
Chemical formula
LiIO3
Appearance White hygroscopic crystals
Odor Odorless
Density 4.487 g/cm3[1]
Melting point 420–450 °C (788–842 °F; 693–723 K)[1][3][5]
Solubility in water
Anhydrous:
89.4 g/100 mL (10 °C)
82.7 g/100 mL (25 °C)
78.4 g/100 mL (40.1 °C)
73 g/100 mL (75.6 °C)[1]
Hemihydrate:
80.2 g/100 mL (18 °C)[2]
Solubility Insoluble in EtOH[3]
Magnetic susceptibility (χ)
−47.0·10−6 cm3/mol
Thermal conductivity 1.27 W/m·K (a-axis)
0.65 W/m·K (c-axis)[1]
Refractive index (nD)
1.8875 (20 °C)
1.6 (RT)
nHe–Ne:
1.8815 (20 °C)[1]
1.5928 (RT)[4]
Structure
Crystal structure
Hexagonal,[3] hP10[6]
Space group
P6322, No. 182[6]
Point group
622[6]
Lattice constant
a = 5.46(9) Å, c = 5.15(5) Å[6]
α = 90°, β = 90°, γ = 120°
Hazards
GHS labelling:
Pictograms
GHS03: OxidizingGHS07: Exclamation markGHS08: Health hazard[7]
Signal word
Danger
Hazard statements
H272, H315, H319, H335, H360[7]
Precautionary statements
P201, P220, P261, P305+P351+P338, P308+P313[7]
NFPA 704 (fire diamond)
[8]
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorusSpecial hazards (white): no code
2
0
2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Lithium iodate (LiIO3) is a negative uniaxial crystal[1] for nonlinear, acousto-optical and piezoelectric applications. It has been utilized for 347 nm ruby lasers.[9][10]

  1. ^ a b c d e f "Rarely Used and Archive Crystals". Nonlinear Optical Crystals: A Complete Survey. 2005. pp. 364–368. doi:10.1007/0-387-27151-1_8. ISBN 978-0-387-27151-4. Archived from the original on 2014-08-08. Retrieved 2014-08-08.
  2. ^ Seidell, Atherton; Linke, William F. (1919). Solubilities of Inorganic and Organic Compounds (2nd ed.). New York City: D. Van Nostrand Company. p. 374.
  3. ^ a b c Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
  4. ^ Polyanskiy, Mikhail. "Refractive index of LiIO3 (Lithium iodate) - Herbst-o". refractiveindex.info. Retrieved 2014-08-08.
  5. ^ Cite error: The named reference spie was invoked but never defined (see the help page).
  6. ^ a b c d Zachariasen, W.H.; Olof, F.A. BartaLars (1931-06-15). "Crystal Structure of Lithium Iodate". Physical Review Letters. 37 (12): 1626–1630. Bibcode:1931PhRv...37.1626Z. doi:10.1103/PhysRev.37.1626.
  7. ^ a b c Sigma-Aldrich Co., Lithium iodate. Retrieved on 2014-08-08.
  8. ^ "SDS of Lithium iodate anhydrous" (PDF). pfaltzandbauer.com. Connecticut, USA: Pfaltz & Bauer, Inc. Archived from the original (PDF) on 2014-08-10. Retrieved 2014-08-08.
  9. ^ Risk, W. P.; Gosnell, T. R.; Nurmikko, A. V. (9 January 2003). Compact Blue-Green Lasers. Cambridge University Press. p. 123. ISBN 978-0-521-52103-1. Retrieved 13 December 2012.
  10. ^ Nikogosyan, David N. (4 January 2005). Nonlinear Optical Crystals: A Complete Survey. Springer. p. 371. ISBN 978-0-387-22022-2. Retrieved 13 December 2012.

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Lithium iodate

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and the effect of nonlinear optical activity was observed in 1979 in lithium iodate crystals. Optical activity is normally observed for transmitted light...

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