In organic chemistry, the Keck asymmetric allylation is a chemical reaction that involves the nucleophilic addition of an allyl group to an aldehyde. The catalyst is a chiral complex that contains titanium as a Lewis acid. The chirality of the catalyst induces a stereoselective addition, so the secondary alcohol of the product has a predictable absolute stereochemistry based on the choice of catalyst. This name reaction is named for Gary Keck.
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In organic chemistry, the Keckasymmetricallylation is a chemical reaction that involves the nucleophilic addition of an allyl group to an aldehyde. The...
catalytic enantioselective methods for carbonyl allylation followed, including work by Umani-Ronchi and Keck. While these methods had a significant impact...
an allylzinc reagent. In 1978, Hoffmann reported the first asymmetric carbonyl allylation using a chiral allylmetal reagent, an allylborane derived from...
Gary E. Keck is an American chemist. Gary Keck received a BS from Bowling Green State University in 1971, a PhD from the University of Wisconsin Madison...
and Nanofluidics. Gary Keck, organic chemist specialized in synthesis of natural products. Developer of Keckasymmetricallylation. Bradley S. Greenberg...
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