In molecular vibrational spectroscopy, a hot band is a band centred on a hot transition, which is a transition between two excited vibrational states, i.e. neither is the overall ground state.[1] In infrared or Raman spectroscopy, hot bands refer to those transitions for a particular vibrational mode which arise from a state containing thermal population of another vibrational mode.[2] For example, for a molecule with 3 normal modes, , and , the transition ← , would be a hot band, since the initial state has one quantum of excitation in the mode. Hot bands are distinct from combination bands, which involve simultaneous excitation of multiple normal modes with a single photon, and overtones, which are transitions that involve changing the vibrational quantum number for a normal mode by more than 1.
^Califano, S. (1976). Vibrational states. New York: Wiley. ISBN 0-471-12996-8.
^Levine, Ira N. (1983). Quantum chemistry. Boston: Allyn and Bacon. p. 68. ISBN 0-205-07793-5.
The HotBand may refer to: The backing band formed by American soul musician Sylvester James in 1973 The backing band for Emmylou Harris from 1974 to...
In molecular vibrational spectroscopy, a hotband is a band centred on a hot transition, which is a transition between two excited vibrational states...
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