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Group 4 element information


Group 4 in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
group 3 ←    → group 5
IUPAC group number 4
Name by element titanium group
CAS group number
(US, pattern A-B-A)
IVB
old IUPAC number
(Europe, pattern A-B)
IVA

↓ Period
4
Image: Titanium crystal bar
Titanium (Ti)
22 Transition metal
5
Image: Zirconium crystal bar
Zirconium (Zr)
40 Transition metal
6
Image: Hafnium crystal bar
Hafnium (Hf)
72 Transition metal
7 Rutherfordium (Rf)
104 Transition metal

Legend
primordial element
synthetic element
Black atomic number: solid

Group 4 is the second group of transition metals in the periodic table. It contains the four elements titanium (Ti), zirconium (Zr), hafnium (Hf), and rutherfordium (Rf). The group is also called the titanium group or titanium family after its lightest member.

As is typical for early transition metals, zirconium and hafnium have only the group oxidation state of +4 as a major one, and are quite electropositive and have a less rich coordination chemistry. Due to the effects of the lanthanide contraction, they are very similar in properties. Titanium is somewhat distinct due to its smaller size: it has a well-defined +3 state as well (although +4 is more stable).

All the group 4 elements are hard, refractory metals. Their inherent reactivity is completely masked due to the formation of a dense oxide layer that protects them from corrosion, as well as attack by many acids and alkalis. The first three of them occur naturally. Rutherfordium is strongly radioactive: it does not occur naturally and must be produced by artificial synthesis, but its observed and theoretically predicted properties are consistent with it being a heavier homologue of hafnium. None of them have any biological role.

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