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Ethylmagnesium bromide information


Ethylmagnesium bromide
Identifiers
CAS Number
  • 925-90-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10254342 checkY
ECHA InfoCard 100.011.935 Edit this at Wikidata
PubChem CID
  • 101914
UNII
  • 5564378HK3 checkY
CompTox Dashboard (EPA)
  • DTXSID80275976 Edit this at Wikidata
InChI
  • InChI=1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1 checkY
    Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M checkY
  • InChI=1/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1/rC2H5BrMg/c1-2-4-3/h2H2,1H3
    Key: TWTWFMUQSOFTRN-QJSJVVHYAJ
SMILES
  • Br[Mg]CC
Properties
Chemical formula
C2H5BrMg
Molar mass 133.271 g·mol−1
Hazards
Safety data sheet (SDS) Oxford MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Ethylmagnesium bromide is a Grignard reagent with formula C2H5MgBr. It is widely used in the laboratory synthesis of organic compounds.

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Ethylmagnesium bromide

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Ethylmagnesium bromide is a Grignard reagent with formula C2H5MgBr. It is widely used in the laboratory synthesis of organic compounds. Apart from acting...

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Michael addition reaction

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6-addition reaction. For example, the image below shows the addition of ethylmagnesium bromide to ethyl sorbate 1 using a copper catalyst with a reversed josiphos...

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Tetraethyltin

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electronics industry. Tetraethyltin can be obtained by reacting ethylmagnesium bromide with tin(IV) chloride: SnCl4 + 4 CH3CH2MgBr → (CH3CH2)4Sn + 4 MgBrCl...

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Ketobemidone

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with bis(2-chloroethyl)methylamine, followed by reaction with ethylmagnesium bromide, and finally O-demethylation with hydrobromic acid. Because of a...

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Diethylmercury

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dimethylmercury. Diethylmercury can be obtained from the reaction between ethylmagnesium bromide and mercury(II) chloride. 2 C2H5MgBr + HgCl2 → Hg(C2H5)2 + MgBr2...

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Kulinkovich reaction

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Formation of 1-Substituted Cyclopropanols in the Reaction of Ethylmagnesium Bromide with Methyl Alkanecarboxylates". Synthesis. 1991 (3): 234. doi:10...

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Organocadmium chemistry

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produced by the reaction of cadmium bromide with two equivalents of the Grignard reagent ethylmagnesium bromide in diethyl ether. Diethylcadmium is a...

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Group 2 organometallic chemistry

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magnesium. Examples of Grignard reagents are phenylmagnesium bromide and ethylmagnesium bromide. These simplified formulas are deceptive: Grignard reagents...

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Nickelocene

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prepared in a one-pot reaction, by deprotonating cyclopentadiene with ethylmagnesium bromide, and adding anhydrous nickel(II) acetylacetonate. A modern synthesis...

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Magnesium

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haloalkanes. Examples of Grignard reagents are phenylmagnesium bromide and ethylmagnesium bromide. The Grignard reagents function as a common nucleophile, attacking...

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DEA list of chemicals

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reagents) (e.g. ethylmagnesium bromide and phenylmagnesium bromide) phencyclidine ortho-Toluidine methaqualone 2-Phenylethyl bromide fentanyl Phenylethanolamine...

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Organomercury chemistry

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results from the reaction of mercury chloride with two equivalents of ethylmagnesium bromide, a conversion that would typically be conducted in diethyl ether...

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Manifaxine

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reaction between 3,5-difluorobenzonitrile [64248-63-1] (1) and ethylmagnesium bromide gives 3,5-difluoropropiophenone [135306-45-5] (2). Halogenation...

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Triethylindium

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compound can be obtained by reacting indium(III) bromide with a diethyl ether solution of Ethylmagnesium bromide: InBr 3 + 3 C 2H 5MgBr → In(C2H5)3 + 3 MgBr...

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Hauser base

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Price, R. D. (1998). "The metallation of imino(triphenyl)phosphorane by ethylmagnesium chloride: The synthesis, isolation and X-ray structure of [Ph3P=NMgCl·O=P(NMe2)3]2"...

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