Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Disodium tetracarbonylferrate is the organoiron compound with the formula Na2[Fe(CO)4]. It is always used as a solvate, e.g., with tetrahydrofuran or dimethoxyethane, which bind to the sodium cation.[1] An oxygen-sensitive colourless solid, it is a reagent in organometallic and organic chemical research. The dioxane solvated sodium salt is known as Collman's reagent, in recognition of James P. Collman, an early popularizer of its use.[2]
^Strong, H.; Krusic, P. J.; San Filippo, J. (1990). Sodium Carbonyl Ferrates, Na2[Fe(CO)4], Na2[Fe2(CO)8], and Na2[Fe3(CO)11]. Bis[μ-Nitrido-Bis(triphenylphosphorus)1+] Undeca-Carbonyltriferrate2−, [(Ph3P)2N]2[Fe3(CO)11]. Inorganic Syntheses. Vol. 28. pp. 203–207. doi:10.1002/9780470132593.ch52. ISBN 0-471-52619-3.
^Miessler, G. L.; Tarr, D. A. (2004). Inorganic Chemistry. Upper Saddle River, NJ: Pearson.
and 9 Related for: Disodium tetracarbonylferrate information
Disodiumtetracarbonylferrate is the organoiron compound with the formula Na2[Fe(CO)4]. It is always used as a solvate, e.g., with tetrahydrofuran or...
reagents such as iron pentacarbonyl, diiron nonacarbonyl and disodiumtetracarbonylferrate. Although iron is generally less active in many catalytic applications...
complexes requires indirect routes, such as the reaction of disodiumtetracarbonylferrate with thiophosgene: Na2Fe(CO)4 + CSCl2 → Fe(CO)4CS + 2 NaCl Complexes...
cluster of three iron atoms at its core. Collman's reagent, disodiumtetracarbonylferrate, is a useful reagent for organic chemistry; it contains iron...
cluster of three iron atoms at its core. Collman's reagent, disodiumtetracarbonylferrate, is a useful reagent for organic chemistry; it contains iron...
(help) Finke, R. G.; Sorrell, T. N. "Nucleophilic Acylation with DisodiumTetracarbonylferrate: Methyl 7-Oxoheptanoate and Methyl 7-oxooctonoate". Organic...
contaminants, many organic compounds, and algae. Ferrates Disodium salt of tetracarbonylferrate. Structure of ferrate(VI), [FeO4]2−. 1-Butyl-3-methylimidazolium...
epidemiologist James P. Collman (born 1932), American chemist Disodiumtetracarbonylferrate, the dioxane solvated sodium salt of which is known as Collman's...
same complex was prepared by the salt metathesis reaction of disodiumtetracarbonylferrate (Na 2Fe(CO)4) with 1,1-bis(chloromethyl)ethylene (H2C=C(CH2Cl)2)...
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