Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Dimethyldioxirane (DMDO) is the organic compound with the formula (CH3)2CO2.[1][2] It is the dioxirane derived from acetone and can be considered as a monomer of acetone peroxide. It is a powerful selective oxidizing agent that finds some use in organic synthesis. It is known only in the form of a dilute solution, usually in acetone, and hence the properties of the pure material are largely unknown.[3]
^"Robert W. Murray Biography". University of Missouri–St. Louis. Retrieved 14 October 2015.
^Murray, Robert W. (July 1989). "Chemistry of dioxiranes. 12. Dioxiranes". Chemical Reviews. 89 (5): 1187–1201. doi:10.1021/cr00095a013.
^Crandall, J. K.; Curc, R; D'Accolti, L; Fusco, C (15 Oct 2005). "Dimethyldioxirane". E-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rd329.pub2. ISBN 0471936235.
Dimethyldioxirane (DMDO) is the organic compound with the formula (CH3)2CO2. It is the dioxirane derived from acetone and can be considered as a monomer...
phenyl sulfoxide, a reaction useful for titration of oxidants such as dimethyldioxirane. Successive oxidation then leads to the sulfone. Nomenclature of Organic...
sulfones. Oxone converts ketones to dioxiranes. The synthesis of dimethyldioxirane (DMDO) from acetone is representative. Dioxiranes are versatile oxidising...
monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane. The dimer is known as diacetone diperoxide (DADP). The trimer is...
of dimethyldioxirane. Cremera, Dieter; Kraka, Elfi; G Szalay, Peter (1998). "Decomposition modes of dioxirane, methyldioxirane and dimethyldioxirane—a...
applications, other peroxide-containing reagents are employed, such as dimethyldioxirane. Depending on the mechanism of the reaction and the geometry of the...
DMD may refer to: Dimethyldioxirane, an organic molecule Disruptive mood dysregulation disorder Doctor of Dental Medicine, an academic degree for the...
polyepoxides can be generated by reaction of COT with peroxy acids or with dimethyldioxirane. Various other addition reactions are also known. Furthermore, polyacetylene...
peroxyacetic acid, peroxyformic acid, potassium peroxymonosulfate (oxone), dimethyldioxirane, which is generated in situ from acetone and potassium peroxymonosulfate...
the alkenes can be epoxidized using mCPBA, peroxybenzoic acid, or dimethyldioxirane (DMDO). Using a peracid (mCPBA or peroxybenzoic acid), the epoxy product...
oxidizing than other dioxiranes due to its stability. Difluorodioxirane Dimethyldioxirane Shi epoxidation Kirschfeld, Andreas; Muthusamy, Sengodagounder; Sander...
Fast and clean post-polymerization modification by oxidation using dimethyldioxirane (DMDO)". Reactive and Functional Polymers. 86: 16–26. Bibcode:2015RFPol...
Ruthenium Complexes with Dimethyldioxirane" [Oxyfunctionalization of Allyl Thioether Ruthenium Complexes with Dimethyldioxirane]. Zeitschrift für Naturforschung...
Another example of a SKIE is the oxidation of benzyl alcohols by dimethyldioxirane where three transition states for different mechanisms were proposed...
catalysts for various organic transformations. Dimesityldioxirane Dimethyldioxirane Shi epoxidation "CAS Common Chemistry". CAS Common Chemistry. 2024-04-09...
coarctate transition state is that of the epoxidation of an olefin by dimethyldioxirane. In this transition state, the oxygen atom transferred to the olefin...
of mixed epoxides when conjugated dienes are used as substrates. Dimethyldioxirane]] can be used as a source of O atomes.DMD of a chiral metal catalyst...
results in the active, toxic form of gambierol.Reaction conditions: (a) Dimethyldioxirane, CH2Cl2, -78 to 0 °C; DIBAL, CH2Cl2, 90% (10:1 mixture). (b) TPAP...
dichlorides to give arylphosphonic amines. Diisobutylamine reacts with dimethyldioxirane to give diisobutylhydroxylamine, as typical for oxidation of secondary...
derivative which has been characterized by X-ray crystallography. Dimethyldioxirane (DMDO) and the still more reactive methyl(trifluoromethyl)dioxirane...
heteroatoms. The most common dioxiranes employed for organic synthesis are dimethyldioxirane (DMD) and trifluoromethyl-methyldioxirane (TFD). The latter is effective...
F.; Ricart, S.; Camps, F.; Messeguer, A.; Moretó, J. M. (1992). "Dimethyldioxirane in Organometallic Chemistry. II. An Improved Procedure for the Oxidative...
can be prepared by oxidation of selenoesters with one equivalent of dimethyldioxirane (DMDO). Use of excess DMDO affords little studied selenonic acids...
trimethylsilyl triflate, and a modified Rubottom oxidation using 3,3-dimethyldioxirane followed by a treatment with camphorsulfonic acid introduced a hydroxyl...
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