Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Diisopinocampheylborane is an organoborane that is useful for asymmetric synthesis. This colourless solid is the precursor to a range of related reagents. The compound was reported in 1961 by Zweifel and Brown in a pioneering demonstration of asymmetric synthesis using boranes. The reagent is mainly used for the synthesis of chiral secondary alcohols. The reagent is often depicted as a monomer but like most hydroboranes, it is dimeric with B-H-B bridges.[1]
^Fürstner, Alois; Bonnekessel, Melanie; Blank, Jarred T.; Radkowski, Karin; Seidel, Günter; Lacombe, Fabrice; Gabor, Barbara; Mynott, Richard (2007). "Total Synthesis of Myxovirescin A1". Chemistry – A European Journal. 13 (31): 8762–8783. doi:10.1002/chem.200700926. PMID 17768720.
and 6 Related for: Diisopinocampheylborane information
Diisopinocampheylborane is an organoborane that is useful for asymmetric synthesis. This colourless solid is the precursor to a range of related reagents...
reagents that are closely related to Alpine borane are 9-BBN and diisopinocampheylborane. This reagent is generated by treating 9-BBN with α-pinene. This...
Singaram Singaram in 2007 Alma mater University of Madras Known for Diisopinocampheylborane TarB-X LAB Reagent Scientific career Institutions Purdue University...
chiraphos, a component of catalysts used for asymmetric hydrogenation: Diisopinocampheylborane is an organoborane that is useful for asymmetric synthesis of secondary...
epoxide by reacting undecanyl aldehydes with (Z)-(γ-chloroallyl)diisopinocampheylborane. Hydroboration and oxidation of this cis-vinyl epoxide yields a...