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Dicopper chloride trihydroxide information


Dicopper chloride trihydroxide
Alpha crystal form
Names
IUPAC name
Dicopper(II) chloride trihydroxide
Preferred IUPAC name
Copper trihydroxyl chloride
Identifiers
CAS Number
  • 1332-65-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10142932
ECHA InfoCard 100.014.158 Edit this at Wikidata
EC Number
  • 215-572-9
PubChem CID
  • 11969527
UNII
  • 76712031PG
CompTox Dashboard (EPA)
  • DTXSID6034475 Edit this at Wikidata
InChI
  • InChI=1S/ClH.2Cu.3H2O/h1H;;;3*1H2/q;2*+2;;;/p-4
    Key: SKQUUKNCBWILCD-UHFFFAOYSA-J
SMILES
  • [OH-].[OH-].[OH-].[Cl-].[Cu+2].[Cu+2]
Properties
Chemical formula
Cu2(OH)3Cl
Molar mass 213.56 g·mol−1
Appearance Green crystalline solid
Density 3.5 g/cm3
Melting point 250 °C; 482 °F; 523 K
Solubility in water
Insoluble in water (pH 6.9 measured by EPA method SW846-9045)
Solubility Insoluble in organic solvents
Structure
Crystal structure
  • Atacamite: orthorhombic
  • Paratacamite: rhombohedral
  • Clinoatacamite: monoclinic
  • Botallackite: monoclinic
Coordination geometry
Distorted octahedral
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)[2]
REL (Recommended)
TWA 1 mg/m3 (as Cu)[2]
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)[2]
Safety data sheet (SDS) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Dicopper chloride trihydroxide is the chemical compound with the chemical formula Cu2(OH)3Cl. It is often referred to as tribasic copper chloride (TBCC), copper trihydroxyl chloride or copper hydroxychloride. It is a greenish crystalline solid encountered in mineral deposits, metal corrosion products, industrial products, art and archeological objects, and some living systems. It was originally manufactured on an industrial scale as a precipitated material used as either a chemical intermediate or a fungicide. Since 1994, a purified, crystallized product has been produced at the scale of thousands of tons per year, and used extensively as a nutritional supplement for animals.

  1. ^ http://www.pyrodata.com/sites/default/files/Copper%20oxychloride.pdf [bare URL PDF]
  2. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).

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