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Dichlorofluoromethane information


Dichlorofluoromethane
Names
Preferred IUPAC name
Dichloro(fluoro)methane
Other names
Dichlorofluoromethane
Fluorodichloromethane
Monofluorodichloromethane
Dichloromonofluoromethane
Freon 21
Refrigerant 21
R 21
HCFC 21
Algofrene Type 5
Arcton 7
Halon 112
UN 1029
Genetron 21
Identifiers
CAS Number
  • 75-43-4 checkY
3D model (JSmol)
  • Interactive image
ChEMBL
  • ChEMBL116813 checkY
ChemSpider
  • 6130 checkY
ECHA InfoCard 100.000.791 Edit this at Wikidata
EC Number
  • 200-869-8
PubChem CID
  • 6370
RTECS number
  • PA8400000
UNII
  • 7GAO4CRJ0B checkY
UN number 1029
CompTox Dashboard (EPA)
  • DTXSID7052498 Edit this at Wikidata
InChI
  • InChI=1S/CHCl2F/c2-1(3)4/h1H checkY
    Key: UMNKXPULIDJLSU-UHFFFAOYSA-N checkY
  • InChI=1/CHCl2F/c2-1(3)4/h1H
    Key: UMNKXPULIDJLSU-UHFFFAOYAU
SMILES
  • ClC(Cl)F
Properties
Chemical formula
CHCl2F
Molar mass 102.92 g/mol
Appearance Colorless gas
Odor Ether-like[1]
Density
  • 1.405 kg/m3 at 9 °C
  • 1.366 kg/m3 at 25 °C
Melting point −135 °C (−211 °F; 138 K)
Boiling point 8.92 °C (48.06 °F; 282.07 K)
Solubility in water
9.420 g/L at 30 °C
log P 1.55
Vapor pressure 160 kPa
Henry's law
constant (kH)
0.19 (mol·kg·bar)−1
Magnetic susceptibility (χ)
−48.8·10−6 cm3/mol
Thermal conductivity 0.0086 W/m·K (300 K)[2]
Hazards
GHS labelling:
Pictograms
GHS04: Compressed GasGHS07: Exclamation mark
Signal word
Warning
Hazard statements
H280, H420
Precautionary statements
P410+P403, P502
Flash point Non-flammable[1]
Autoignition
temperature
522 °C (972 °F; 795 K)
Lethal dose or concentration (LD, LC):
LC50 (median concentration)
  • >800,000 mg/m3 (mouse, 2 hr)
  • 49,900 ppm (rat, 4 hr)[3]
LCLo (lowest published)
  • 100,000 ppm (guinea pig, <1 hr)
  • 100,000 ppm (mouse, <1 hr)[3]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1000 ppm (4200 mg/m3)[1]
REL (Recommended)
TWA 10 ppm (40 mg/m3)[1]
IDLH (Immediate danger)
5000 ppm[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Dichlorofluoromethane or Freon 21 or R 21 is a halomethane or hydrochlorofluorocarbon with the formula CHCl2F. It is a colorless and odorless gas. It is produced by fluorination of chloroform using a catalyst such as antimony trifluoride:[4]

CHCl3 + HF → CHCl2F + HCl
  1. ^ a b c d e NIOSH Pocket Guide to Chemical Hazards. "#0197". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ Touloukian, Y.S., Liley, P.E., and Saxena, S.C. Thermophysical properties of matter - the TPRC data series. Volume 3. Thermal conductivity - nonmetallic liquids and gases. Data book. 1970.
  3. ^ a b "Dichloromonofluoromethane". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  4. ^ Cite error: The named reference Ullmann was invoked but never defined (see the help page).

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Dichlorofluoromethane

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Dichlorofluoromethane or Freon 21 or R 21 is a halomethane or hydrochlorofluorocarbon with the formula CHCl2F. It is a colorless and odorless gas. It...

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Halon

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(carbon tetrachloride) Halon 1103 (tribromofluoromethane) Halon 112 (dichlorofluoromethane) Halon 1201 (bromodifluoromethane) Halon 1202 (dibromodifluoromethane)...

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Chlorofluorocarbon

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CCl2F2 Chlorotrifluoromethane Freon-13, R-13, CFC-13 −81 CClF3 Dichlorofluoromethane R-21, HCFC-21 8.9 CHCl2F Chlorodifluoromethane R-22, HCFC-22 −40...

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Chloroform

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CHF3 Bromoform CHBr3 Iodoform CHI3 Chlorodifluoromethane CHF2Cl Dichlorofluoromethane CHFCl2 Bromodichloromethane CHCl2Br Dibromochloromethane CHClBr2...

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List of gases

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Pentafluorosulfanyl hypochlorite[citation needed] SF5OCl 8.9 178.5 Dichlorofluoromethane CHCl2F 8.92 −135 103 75-43-4 ethylgermane CH3CH2GeH3 9.2 104.66...

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Flammability limit

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13 °C 413 °C 1,1-Dichloroethene 6.5 15.5 IA −10 °C Flammable gas Dichlorofluoromethane 54.7 Non flammable, −36.1 °C 552 °C Dichloromethane, methylene chloride...

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List of refrigerants

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(Trichloromethane) CHCl3 67-66-3 0.51 31 119.4 61.2 262.35 5,480 HCFC R-21 Dichlorofluoromethane CHFCl2 75-43-4 1.7 0.04 148 100? B1 102.9 8.92 178.45 5,180 HCFC...

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List of UN numbers 1001 to 1100

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2.2 Dichlorodifluoromethane or Refrigerant gas R 12 UN 1029 2.2 Dichlorofluoromethane or Refrigerant gas R 21 UN 1030 2.1 1,1-Difluoroethane or Refrigerant...

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Chlorofluoromethane

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import were banned on 1 January 2015. Pyrolysis of a mixture of dichlorofluoromethane and chlorofluoromethane gives hexafluorobenzene: 3 CHCl2F + 3 CH2ClF...

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R21

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regional road (Montenegro) R21 (South Africa) R21 highway (Russia) Dichlorofluoromethane, a refrigerant R21: Harmful in contact with skin, a risk phrase...

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Fluoroform

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CHCl3 Bromoform CHBr3 Iodoform CHI3 Chlorodifluoromethane CHF2Cl Dichlorofluoromethane CHFCl2 Bromodichloromethane CHCl2Br Dibromochloromethane CHClBr2...

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