Dichlorofluoromethane Fluorodichloromethane Monofluorodichloromethane Dichloromonofluoromethane Freon 21 Refrigerant 21 R 21 HCFC 21 Algofrene Type 5 Arcton 7 Halon 112 UN 1029 Genetron 21
Identifiers
CAS Number
75-43-4Y
3D model (JSmol)
Interactive image
ChEMBL
ChEMBL116813Y
ChemSpider
6130Y
ECHA InfoCard
100.000.791
EC Number
200-869-8
PubChem CID
6370
RTECS number
PA8400000
UNII
7GAO4CRJ0BY
UN number
1029
CompTox Dashboard (EPA)
DTXSID7052498
InChI
InChI=1S/CHCl2F/c2-1(3)4/h1HY
Key: UMNKXPULIDJLSU-UHFFFAOYSA-NY
InChI=1/CHCl2F/c2-1(3)4/h1H
Key: UMNKXPULIDJLSU-UHFFFAOYAU
SMILES
ClC(Cl)F
Properties
Chemical formula
CHCl2F
Molar mass
102.92g/mol
Appearance
Colorless gas
Odor
Ether-like[1]
Density
1.405kg/m3 at 9°C
1.366kg/m3 at 25°C
Melting point
−135 °C (−211 °F; 138 K)
Boiling point
8.92 °C (48.06 °F; 282.07 K)
Solubility in water
9.420g/L at 30°C
log P
1.55
Vapor pressure
160kPa
Henry's law constant (kH)
0.19(mol·kg·bar)−1
Magnetic susceptibility (χ)
−48.8·10−6cm3/mol
Thermal conductivity
0.0086W/m·K (300K)[2]
Hazards
GHS labelling:
Pictograms
Signal word
Warning
Hazard statements
H280, H420
Precautionary statements
P410+P403, P502
Flash point
Non-flammable[1]
Autoignition temperature
522 °C (972 °F; 795 K)
Lethal dose or concentration (LD, LC):
LC50 (median concentration)
>800,000mg/m3 (mouse, 2hr)
49,900ppm (rat, 4hr)[3]
LCLo (lowest published)
100,000ppm (guinea pig, <1hr)
100,000ppm (mouse, <1hr)[3]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1000ppm (4200mg/m3)[1]
REL (Recommended)
TWA 10ppm (40mg/m3)[1]
IDLH (Immediate danger)
5000ppm[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound
Dichlorofluoromethane or Freon 21 or R 21 is a halomethane or hydrochlorofluorocarbon with the formula CHCl2F. It is a colorless and odorless gas. It is produced by fluorination of chloroform using a catalyst such as antimony trifluoride:[4]
CHCl3 + HF → CHCl2F + HCl
^ abcdeNIOSH Pocket Guide to Chemical Hazards. "#0197". National Institute for Occupational Safety and Health (NIOSH).
^Touloukian, Y.S., Liley, P.E., and Saxena, S.C. Thermophysical properties of matter - the TPRC data series. Volume 3. Thermal conductivity - nonmetallic liquids and gases. Data book. 1970.
^ ab"Dichloromonofluoromethane". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
^Cite error: The named reference Ullmann was invoked but never defined (see the help page).
and 11 Related for: Dichlorofluoromethane information
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