Cyclotetradecaheptaene information

Cyclotetradecaheptaene
Names
	IUPAC name (1E,3Z,5E,7Z,9E,11E,13Z)-cyclotetradeca-1,3,5,7,9,11,13-heptaene
	Other names [14]Annulene
Identifiers
CAS Number	2873-14-5 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:37523 ;
ChemSpider	10160742 ;
PubChem CID	11988275;
CompTox Dashboard (EPA)	DTXSID20475276 ;
	InChI InChI=1S/C14H14/c1-2-4-6-8-10-12-14-13-11-9-7-5-3-1/h1-14H/b2-1-,3-1-,4-2+,5-3+,6-4+,7-5+,8-6-,9-7-,10-8+,11-9+,12-10+,13-11+,14-12-,14-13- Key: RYQWRHUSMUEYST-ILUIUFOYSA-N ;
	SMILES C1C=CC=CC=CC=CC=CC=CC=1;
Properties
Chemical formula	C14H14
Molar mass	182.266 g·mol−1
Appearance	dark-red needle-like crytals
Solubility in water	Insoluble
Solubility in benzene	Soluble
Structure
Crystal structure	monoclinic
Space group	P21/c, No. 14
Lattice constant	a = 8.640 Å, b = 4.376 Å, c = 14.997 Å α = 90°, β = 106°, γ = 90°
Formula units (Z)	2 molecules per cell
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	Flammable, reactive
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Cyclotetradecaheptaene, often referred to as [14]annulene, is a hydrocarbon with molecular formula C₁₄H₁₄, which played an important role in the development of criteria (Hückel's rule) for aromaticity, a stabilizing property of central importance in physical organic chemistry. It forms dark-red needle-like crystals.^[1]

^ ^a ^b Chiang, Chian C.; Paul, Iain C. (1972). "Crystal and Molecular Structure of [14]Annulene". J. Am. Chem. Soc. 94 (13): 4741–4743. doi:10.1021/ja00768a058.

[cryst-1] Chiang, Chian C.; Paul, Iain C. (1972). "Crystal and Molecular Structure of [14]Annulene". J. Am. Chem. Soc. 94 (13): 4741–4743. doi:10.1021/ja00768a058.

Cyclotetradecaheptaene information

and 4 Related for: Cyclotetradecaheptaene information

Cyclotetradecaheptaene

Annulene

C14H14

Aromaticity