Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Cyclooctadiene iridium chloride dimer is an organoiridium compound with the formula [Ir(μ2-Cl)(COD)]2, where COD is the diene 1,5-cyclooctadiene (C8H12). It is an orange-red solid that is soluble in organic solvents. The complex is used as a precursor to other iridium complexes, some of which are used in homogeneous catalysis.[1] The solid is air-stable but its solutions degrade in air.
^J. Hartwig, "Organotransition Metal Chemistry: From Bonding to Catalysis" University Science Books, 2009. ISBN 978-1891389535.
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Cyclooctadieneiridiumchloridedimer is an organoiridium compound with the formula [Ir(μ2-Cl)(COD)]2, where COD is the diene 1,5-cyclooctadiene (C8H12)...
Cyclooctadiene rhodium chloridedimer is the organorhodium compound with the formula Rh2Cl2(C8H12)2, commonly abbreviated [RhCl(COD)]2 or Rh2Cl2(COD)2...
Cyclooctadieneiridium methoxide dimer is an organoiridium compound with the formula Ir2(OCH3)2(C8H12)2, where C8H12 is the diene 1,5-cyclooctadiene. It...
Important compounds of iridium are chlorides and iodides in industrial catalysis. Iridium is a component of some OLEDs. Iridium is found in meteorites...
Iridium compounds are compounds containing the element iridium (Ir). Iridium forms compounds in oxidation states between −3 and +9, but the most common...
is that of gramine with phenylboronic acid catalyzed by cyclooctadiene rhodium chloridedimer: Boronic esters are oxidized to the corresponding alcohols...
Crabtree's catalyst is a highly active catalyst featuring iridium. Cyclooctadiene rhodium chloridedimer, Rh2Cl2(cod)2 is a precursor to many homogeneous catalysts...
related nickel(0) complex bis(cyclooctadiene)nickel(0) is a useful catalyst in organonickel chemistry because the cyclooctadiene (or cod) ligands are easily...
synthetic intermediates, are produced commercially by ethenolysis of 1,5-cyclooctadiene and cyclooctene. The catalyst is derived from Re2O7 on alumina. Synthesis...
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