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Coffinite information


Coffinite
Pitchblende and coffinite in a sample from a Czech mine
General
CategoryNesosilicate
Formula
(repeating unit)
U(SiO4)1−x(OH)4x
IMA symbolCof[1]
Strunz classification9.AD.30
Crystal systemTetragonal
Crystal classDitetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Space groupI41/amd
Unit cella = 6.97 Å, c = 6.25 Å; Z = 4
Identification
ColorBlack (from organic inclusions; pale to dark brown in thin section
Crystal habitRarely as crystals, commonly as colloform to botryoidal incrustations, fibrous, pulverulent masses
FractureIrregular to subconchoidal
TenacityBrittle to friable
Mohs scale hardness5–6
LusterDull to adamantine
StreakGrayish black
DiaphaneityOpaque, transparent on thin edges
Specific gravity5.1
Optical propertiesUniaxial (+/−)
Refractive indexnα = 1.730–1.750 nβ = 1.730–1.750
Birefringenceδ = 1.730
PleochroismModerate; pale yellow-brown parallel to and medium brown perpendicular to long axis
Alters toMetamict
Other characteristics Radioactive 72.63% (U)
References[2][3][4][5][6][7][8][9][10][11][12][13][14]

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.

It occurs as black incrustations, dark to pale-brown in thin section. It has a grayish-black streak. It has a brittle to conchoidal fracture. The hardness of coffinite is between 5 and 6.

It was first described in 1954 for an occurrence at the La Sal No. 2 Mine, Beaver Mesa, Mesa County, Colorado, US,[5] and named for American geologist Reuben Clare Coffin (1886–1972).[3] It has widespread global occurrence in Colorado Plateau-type uranium ore deposits of uranium and vanadium. It replaces organic matter in sandstone and in hydrothermal vein type deposits.[3] It occurs in association with uraninite, thorite, pyrite, marcasite, roscoelite, clay minerals and amorphous organic matter.[3]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Mineralienatlas
  3. ^ a b c d Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Coffinite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 19 June 2022.
  4. ^ Webmineral data
  5. ^ a b Coffinite, Mindat.org
  6. ^ Stieff, L.R.; Stern, T.W; Sherwood, A.M. (1955). "Preliminary Description of Coffinite – A New Uranium Mineral". Science. 121 (3147): 608–609. Bibcode:1955Sci...121..608S. doi:10.1126/science.121.3147.608-a. hdl:2027/mdp.39015095016906.
  7. ^ Fuchs, L.H.; Gebert, E. (1958). "X-Ray Studies of Synthetic Coffinite, Thorite and Uranothorites". American Mineralogist. 43: 243–248.
  8. ^ Stieff, L.R.; Stern, T.W; Sherwood, A.M. (1956). "Coffinite, a Uranous Silicate with Hydroxyl Substitution – A New Mineral". American Mineralogist. 41: 675–688.
  9. ^ Hansley, P.L.; Fitzpatrick, J.J. (1989). "Compositional and Crystallographic Data on REE-Bearing Coffinite from the Grants Uranium Region, Northwestern New-Mexico". American Mineralogist. 74: 263–270.
  10. ^ Moench, R.H. (1962). "Properties and Paragenesis af Coffinite from Woodrow Mine, New Mexico". American Mineralogist. 47: 26–33.
  11. ^ Min, M.Z.; Fang, C.Q.; Fayek, M. (2005). "Petrography and Genetic History of Coffinite and Uraninite from the Liueryiqi Granite-Hosted Uranium Deposit, SE China". Ore Geology Reviews. 26 (3–4): 187–197. doi:10.1016/j.oregeorev.2004.10.006.
  12. ^ Zhang, F. X.; Pointeau, V.; Shuller, L. C.; et al. (2009). "Response of Synthetic Coffinite to Energetic Ion Beam Irradiation". American Mineralogist. 94: 916–920. doi:10.2138/am.2009.3111. S2CID 73581946.
  13. ^ Hoekstra, H.R.; Fuchs, L.H. (1956). "Synthesis of Coffinite-USiO4". Science. 123 (3186): 105. Bibcode:1956Sci...123..105H. doi:10.1126/science.123.3186.105.
  14. ^ Guo X.; Szenknect S.; Mesbah A.; Labs S.; Clavier N.; Poinssot C.; Ushakov S.V.; Curtius H.; Bosbach D.; Rodney R.C.; Burns P.; Navrotsky A. (2015). "Thermodynamics of Formation of Coffinite, USiO4". Proc. Natl. Acad. Sci. USA. 112 (21): 6551–6555. Bibcode:2015PNAS..112.6551G. doi:10.1073/pnas.1507441112. PMC 4450415. PMID 25964321.

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