Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Bullvalene is a hydrocarbon with the chemical formula C10H10. The molecule has a cage-like structure formed by the fusion of one cyclopropane and three cyclohepta-1,4-diene rings. Bullvalene is unusual as an organic molecule due to the C−C and C=C bonds forming and breaking rapidly on the NMR timescale; this property makes it a fluxional molecule.[1]
^Addison Ault (2001). "The Bullvalene Story. The Conception of Bullvalene, a Molecule That Has No Permanent Structure". Journal of Chemical Education. 78 (7): 924. Bibcode:2001JChEd..78..924A. doi:10.1021/ed078p924.
Bullvalene is a hydrocarbon with the chemical formula C10H10. The molecule has a cage-like structure formed by the fusion of one cyclopropane and three...
1016/S0040-4020(01)99207-5.[dead link] Ault, Addison (2001). "The Bullvalene Story. The Conception of Bullvalene, a Molecule That Has No Permanent Structure". J. Chem...
Cope rearrangement causes the fluxional states of the molecules in the bullvalene family. The Cope rearrangement is the prototypical example of a concerted...
and oxepin. Other examples of this type of tautomerism can be found in bullvalene, and in open and closed forms of certain heterocycles, such as organic...
synthesis and the Parikh-Doering oxidation, prediction of the existence of bullvalene as a fluxional molecule, and elucidation of the mechanism of the Baeyer–Villiger...
highlighted below, other classic examples include the Cope rearrangement in bullvalene and the chair inversion in cyclohexane. For processes that are too slow...
6 aromatic membered rings: the acenes Triquinacene is isomeric with: bullvalene, diisopropenyldiacetylene IUPAC, Compendium of Chemical Terminology, 2nd...
of polyunsaturated hydrocarbons, e.g. cycloheptatriene, azulene, and bullvalene. In the case of cyclooctatetraene (COT), derivatives include Fe(COT)2...
at McMaster University. A polycyclic ketone "barbaralone", related to bullvalene was named after her. Ferrier attended George Heriot's School for all of...
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