Dicopper complex derived from diformylcresol and ethylenediamine.
In coordination chemistry, a binucleating ligand binds two metals. Much attention has been directed toward such ligands that hold metals side-by-side, such that the pair of metals can bind substrates cooperatively.[1]
A variety of metalloenzymes feature bimetallic active sites. Examples include superoxide dismutase, urease, nickel-iron hydrogenase. Many Non-heme iron proteins have diiron active sites, e.g. ribonucleotide reductase and hemerythrin.
^Gavrilova, A. L.; Bosnich, B., "Principles of Mononucleating and Binucleating Ligand Design", Chem. Rev. 2004, volume 104, 349-383. doi:10.1021/cr020604g
and 9 Related for: Binucleating ligand information
multimetallic assemblies. Binucleatingligands bind two metal ions. Usually binucleatingligands feature bridging ligands, such as phenoxide, pyrazolate...
In coordination chemistry, a binucleatingligand binds two metals. Much attention has been directed toward such ligands that hold metals side-by-side,...
forms bimetallic complexes Triacetylmethane 2,4,6-Heptanetrione, a binucleatingligand. C 5H 7O− 2 in some cases also binds to metals through the central...
Ligands", Organometallics 2012, 31, 3825. doi:10.1021/om300279t Gavrilova, A. L.; Bosnich, B. (2004). "Principles of Mononucleating and Binucleating Ligand...
factors force these ligands to bind to two separate metals, i.e., they are binucleatingligands. Chelating diisocyanide ligands require elaborate backbones...
condenses with amines to give diimines that are widely studied as binucleatingligands. Formyl groups (aldehydes) are fairly strong deactivating groups...
had infiltrating lymphocytes that expressed PD-L1 (i.e. programmed death-ligand 1), a protein that when upregulated may allow cancer cells to evade the...
examination, they may have one or more cytoplasmic projections and/or be binucleate. Characteristically they contain eosinophilic granules that stain darkly...
There they serve as transcription factors when bound to their ligand; in the absence of a ligand, many such receptors function as histone deacetylases that...
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