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Autunite information


Autunite
Autunite from Daybreak Mine, Washington
General
CategoryPhosphate minerals
Formula
(repeating unit)
Ca(UO2)2(PO4)2·10–12H2O
IMA symbolAut[1]
Strunz classification8.EB.05
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPnma
Unit cella = 14.0135(6),
b = 20.7121(8),
c = 6.9959(3) [Å]; Z = 4
Identification
Formula mass986.26 g/mol
ColorLemon-yellow to sulfur-yellow, greenish yellow to pale green; may be dark green to greenish black
Crystal habitTabular crystals, foliated or scaly aggregates, and in crusts
TwinningRare on {110}
Cleavage{001} perfect, {100} and {010} poor
Fractureuneven
Mohs scale hardness2–2.5
LusterVitreous – pearly
StreakPale yellow
DiaphaneityTransparent to translucent
Specific gravity3.1–3.2
Density3.15
Optical propertiesBiaxial (−)
Refractive indexnα = 1.553 – 1.555 nβ = 1.575 nγ = 1.577 – 1.578
Birefringenceδ = 0.003
PleochroismX = colorless to pale yellow; Y = Z = yellow to dark yellow
2V angleMeasured: 10° to 53°
Ultraviolet fluorescenceStrong yellow-green fluorescence in UV; Radioactive
SolubilitySoluble in acids
Alters toDehydrates in air
Other characteristicsPseudotetragonal for synthetic material, Radioactive
References[2][3]

Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness of 2–2+12.[4][5] Autunite crystallizes in the orthorhombic system and often occurs as tabular square crystals, commonly in small crusts or in fan-like masses. Due to the moderate uranium content of 48.27% it is radioactive and also used as uranium ore. Autunite fluoresces bright green to lime green under UV light. The mineral is also called calco-uranite, but this name is rarely used and effectively outdated.[6]

Autunite was discovered in 1852 near Autun, France, which is also autunite's namesake. It occurs as an oxidation product of uranium minerals in granite pegmatites and hydrothermal deposits. Associate minerals include metaautunite, torbernite, phosphuranylite, saleeite, uranophane and sabugalite.[3]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Mindat.org
  3. ^ a b Handbook of Mineralogy
  4. ^ Barthelmy, Dave. "Autunite Mineral Data". webmineral.com. Retrieved 2018-01-26.
  5. ^ "Autunite: Autunite mineral information and data". www.mindat.org. Retrieved 2018-04-28.
  6. ^ "Autunite" . Encyclopædia Britannica. Vol. 03 (11th ed.). 1911.

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Autunite

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Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness...

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Torbernite

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secondary mineral. The chemical formula of torbernite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+ cation. Torbernite tends to dehydrate...

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Phosphate mineral

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Fe)Al2(PO4)2(OH)2 Wavellite Al3(PO4)2(OH)3·5H2O Turquoise CuAl6(PO4)4(OH)8·5H2O Autunite Ca(UO2)2(PO4)2·10-12H2O Phosphophyllite Zn2(Fe,Mn)(PO4)2•4H2O Struvite...

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Uranium ore

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various deposits. These include carnotite, tyuyamunite, torbernite and autunite. The davidite-brannerite-absite type uranium titanates, and the...

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Uranium

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minerals, including uraninite (the most common uranium ore), carnotite, autunite, uranophane, torbernite, and coffinite. Significant concentrations of uranium...

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Fluorescence

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in a yellow green, and is the cause of fluorescence of minerals such as autunite or andersonite, and, at low concentration, is the cause of the fluorescence...

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List of minerals

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Aubertite Augelite Augite Aurichalcite Auricupride Aurostibite Austinite Autunite Avicennite Avogadrite Awaruite Axinite (mineral group) Azurite Varieties...

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Uranium mining in the United States

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made small shipments in 1954 and 1955. Uranium occurs as uraninite and autunite in shear zones in granodiorite. Accessory minerals include fluorite and...

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Zeunerite

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mineral with formula Cu(UO2)2(AsO4)2·(10-16)H2O. It is a member of the autunite group. The associated mineral metazeunerite is a dehydration product of...

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Metatorbernite

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closely associated with torbernite, but is also found amongside autunite, meta-autunite and uraninite. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols"...

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Crystal twinning

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Structures and Synthesis of the Copper-Dominant Members of the Autunite and Meta-Autunite Groups: Torbernite, Zeunerite, Metatorbernite and Metazeunerite"...

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Hillman Hall of Minerals and Gems

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Autunite, Washington state...

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Mineral

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elements could be a defining constituent, such as uranium in uraninite, autunite, and carnotite, or present as trace impurities, as in zircon. The decay...

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Autun

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beginning of the modern oil-shale industry. In 1852, the uranium mineral autunite was first discovered near Autun, and named for the town. Autun is the main...

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Uramphite

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the "meta-autunite group" with number VII/E.02 together with abernathyite, bassetite, chernikovite, lehnerite, meta-ankoleite, meta-autunite, meta-heinrichite...

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William Gregor

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analysed wavellite, tourmaline, and the uranium minerals torbernite and autunite, the arsenate scorodite, the lead mineral mimetite and the nickel mineral...

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Ruggles Mine

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Specimens of the rare uranium minerals, such as uranophane, torbernite, and autunite, have been found. Sam Ruggles (3 August 1770 – 27 May 1843) started the...

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Biomineralization

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physical cue to coordinate ECM production by the bacterial community. Autunite crystal Biomineralization may be used to remediate groundwater contaminated...

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Alfred Carlton Gilbert

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U-238 Atomic Energy Laboratory, which contained radioactive ore samples of autunite, carnotite, torbernite and uraninite.: 179  In 1908, he married Mary Thompson...

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List of mineral symbols

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Agjrs Austinite Aus Aheylite Ahe Amarantite Ama Argentoliveingite Aliv Autunite Aut Ahlfeldite Afe Amarillite Amr Argentopearceite Apea Avdeevite Avd Ahrensite...

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Uranium mining

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uranium was produced from 1825 until 1898. In 1852, the uranium mineral autunite from the Massif Central was identified. Around 1850, uranium mining began...

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Aguiliri

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Quechua orogeny, forming the Aguiliri centre.: 3–4  The uranium mineral autunite is found in the country rock surrounding the dome. This mineral was probably...

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Actinide

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dozens of other uranium minerals such as carnotite (KUO2VO4·3H2O) and autunite (Ca(UO2)2(PO4)2·nH2O). The isotopic composition of natural uranium is 238U...

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Uranyl

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include: silicates: uranophane (H3O)2Ca(UO2)2(SiO4)·3H2O) phosphates: autunite (Ca(UO2)2(PO4)2·8–12H2O), torbernite (Cu(UO2)2(PO4)·8–12H2O) arsenates:...

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Uranium mining in Colorado

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Formation and the subjacent Precambrian schist. The veins contain pitchblende, autunite and uranophane, with accessory marcasite and barite. Extraction started...

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Metarauchite

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member of the autunite group, found at the Jáchymov ore district (type locality), Czech Republic and in Schneeberg, Germany. The autunite group is a group...

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Midnite Mine

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depressions or flexures in the granitic contact. Shallow ore is mainly autunite. Deeper ore is pitchblende and coffinite with abundant pyrite and marcasite...

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