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Antiperovskites (or inverse perovskites) is a type of crystal structure similar to the perovskite structure that is common in nature.[1] The key difference is that the positions of the cation and anion constituents are reversed in the unit cell structure. In contrast to perovskite, antiperovskite compounds consist of two types of anions coordinated with one type of cation. Antiperovskite compounds are an important class of materials because they exhibit interesting and useful physical properties not found in perovskite materials, including as electrolytes in solid-state batteries.[2]
^Krivovichev, Sergey (2008-01-01). "Minerals with antiperovskite structure: A review". Zeitschrift für Kristallographie. 223 (1–02): 109–113. Bibcode:2008ZK....223..109K. doi:10.1524/zkri.2008.0008. S2CID 94097089.
^Xia W, Zhao Y, Zhao F, et al. Antiperovskite Electrolytes for Solid-State Batteries. Chem Rev. 2022;122(3):3763-3819.
Antiperovskites (or inverse perovskites) is a type of crystal structure similar to the perovskite structure that is common in nature. The key difference...
nitrogen increases the melting point to roughly 1270 °C. Mn4N is an antiperovskite superlattice with Pearson symbol cP5 and space group Fm3m, the same...
3.5. The crystal is monoclinic and is a type of naturally occurring antiperovskite. Kogarkoite is named after the Russian petrologist Lia Nikolaevna Kogarko...
cleavage and a trigonal crystal system. It is also a naturally occurring antiperovskite. Common associates of arctite include aegirine, natisite, lomonosovite...
"Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan. 86 (10): 104706...
phosphorus admixture. Crystal structure of nabimusaite is modular. It is of antiperovskite type. It is composed of hatrurite-like modules [Ca12(SiO4)4O2F]3+ anions...
Kloß, Simon D.; Weidmann, Niels; Schnick, Wolfgang (2017-04-03). "Antiperovskite Nitridophosphate Oxide Ho 3 [PN 4 ]O by High-Pressure Metathesis". European...
(2005). "Sr 11 Ge 4 N 6 : a new nitride composed of [GeN 2 Sr 7 ] 4+ antiperovskite-type slabs and [Sr 4 Ge] 4+ layers, separated by sheets of bent [Ge...
modular structure and disorder of a new mineral with single and triple antiperovskite layers". Acta Crystallographica Section B. 74 (6): 492–501. Bibcode:2018AcCrB...
Sergey V. (November 2015). "Order–disorder phase transition in the antiperovskite-type structure of synthetic kogarkoite, Na3SO4F". Journal of Solid State...
Naturforschung, volume 34b, 1979, pp. 238–241. R. Weihrich, I. Anusca: Half Antiperovskites III: crystallographic and electronic structure effects in Co-Shandites...
stabilities of and mechanism of superionic transport in lithium-rich antiperovskites". Physical Review B. 87 (13): 134303. Bibcode:2013PhRvB..87m4303Z....
modular structure and disorder of a new mineral with single and triple antiperovskite layers". Acta Crystallographica Section B. 74 (6): 492–501. doi:10...
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