In organophosphorus chemistry, an aminophosphine is a compound with the formula R3−nP(NR2)n where R = H or an organic substituent, and n = 0, 1, 2. At one extreme, the parents H2PNH2 and P(NH2)3 are lightly studied and fragile, but at the other extreme tris(dimethylamino)phosphine (P(NMe2)3) is commonly available. Intermediate members are known, such as Ph2PN(H)Ph. These compounds are typically colorless and reactive toward oxygen. They have pyramidal geometry at phosphorus.[1]
^Mateo Alajarín; Carmen López-Leonardo; Pilar Llamas-Lorente (2005). "The Chemistry of Phosphinous Amides (Aminophosphanes): Old Reagents with New Applications". Top. Curr. Chem. Topics in Current Chemistry. 250: 77–106. doi:10.1007/b100982. ISBN 978-3-540-22498-3.
In organophosphorus chemistry, an aminophosphine is a compound with the formula R3−nP(NR2)n where R = H or an organic substituent, and n = 0, 1, 2. At...
superbase with the formula P(MeNCH2CH2)3N. A colorless oil, it is an aminophosphine although its inventor John Verkade called it proazaphosphatrane. The...
complexes are potential catalysts for the synthesis of polyethylene. Aminophosphine Phosphazene Dehnicke, Kurt; Krieger, Matthias; Massa, Werner (February...
"Modularly Designed Transition Metal PNP and PCP Pincer Complexes based on Aminophosphines: Synthesis and Catalytic Applications". Accounts of Chemical Research...
0) mixed-valence complex according to the Robin-Day classification. Aminophosphine ligands with biferroceno substituents have been prepared as catalysts...
1021/cr00069a002. ISSN 0009-2665. Dahl, Otto (1982-01-01). "Reactions of aminophosphines with trifluormethanesulfonic acid: phosphenium ion (two-coordinate...
Louis (2001). "Synthesis and Characterisation of Monophosphines and Aminophosphines Bearing Chiral Phosphetane Units". Synthesis. 2001 (14): 2095–2104...
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