Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Allyltrimethylsilane is the organosilicon compound with the formula (CH3)3SiCH2CH=CH2. The molecule consists of the trimethylsilyl group attached to allyl group. This colorless liquid is used in organic synthesis.[2]
Allyltrimethylsilane is the organosilicon compound with the formula (CH3)3SiCH2CH=CH2. The molecule consists of the trimethylsilyl group attached to allyl...
include carbonyl allylation with allylmetallic reagents, such as allyltrimethylsilane, or the iridium-catalyzed Krische allylation. Allylation can be effected...
reaction of carbon electrophiles (such as a ketone shown here) with allyltrimethylsilane catalyzed by strong Lewis acids. The reaction achieves results similar...
Active Organocatalysts Enable a Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes". Angewandte Chemie International Edition. 55 (42)....
carbon atoms), dimethyl acetylenedicarboxylate (4 carbon atoms) and allyltrimethylsilane (2 equivalents, 6 carbon atoms). In the first leg of the procedure...
acyclic transition state. The reaction of β-alkoxy aldehyde with allyltrimethylsilane showed good selectivity for the anti-1,3-diol, which was explained...
employed a chiral boron Lewis acid-catalyst in combination with allyltrimethylsilane. Numerous other catalytic enantioselective methods for carbonyl allylation...
Trost Barry M (1979). "New conjunctive reagents. 2-Acetoxymethyl-3-allyltrimethylsilane for methylenecyclopentane annulations catalyzed by palladium(0)"...
employed a chiral boron Lewis acid-catalyst in combination with allyltrimethylsilane. Numerous catalytic enantioselective methods for carbonyl allylation...
center after loss of the silyl group. In 1948, it was discovered that allyltrimethylsilane reacts with hydrobromic acid to give (2-bromopropyl)trimethylsilane...
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