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Diethylene glycol information


Diethylene glycol
Skeletal formula of diethylene glycol
Ball-and-stick model of the diethylene glycol molecule
Names
IUPAC name
2,2′-Oxydiethanol[1]
Other names
2,2′-Oxybis(ethan-1-ol)
2-(2-Hydroxyethoxy)ethan-1-ol
Diethylene glycol
Ethylene diglycol
Diglycol
2,2′-Oxybisethanol
2,2′-Oxydiethanol
3-Oxa-1,5-pentanediol
Dihydroxy diethyl ether
Digenos
Digol
Identifiers
CAS Number
  • 111-46-6 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:46807 checkY
ChemSpider
  • 13835180 checkY
ECHA InfoCard 100.003.521 Edit this at Wikidata
KEGG
  • C14689 checkY
PubChem CID
  • 8117
UNII
  • 61BR964293 checkY
CompTox Dashboard (EPA)
  • DTXSID8020462 Edit this at Wikidata
InChI
  • InChI=1S/C4H10O3/c5-1-3-7-4-2-6/h5-6H,1-4H2 checkY
    Key: MTHSVFCYNBDYFN-UHFFFAOYSA-N checkY
  • InChI=1/C4H10O3/c5-1-3-7-4-2-6/h5-6H,1-4H2
    Key: MTHSVFCYNBDYFN-UHFFFAOYAK
SMILES
  • OCCOCCO
Properties
Chemical formula
C4H10O3
Molar mass 106.12 g/mol
Appearance Colorless liquid
Density 1.118 g/mL
Melting point −10.45 °C (13.19 °F; 262.70 K)
Boiling point 244 to 245 °C (471 to 473 °F; 517 to 518 K)
Solubility in water
miscible
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable, mildly toxic
GHS labelling:
Pictograms
GHS02: FlammableGHS06: ToxicGHS07: Exclamation mark
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
1
0
Flash point Combustible
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2 — 25 g/kg (orally, rats)[2]
Related compounds
Related diols
ethylene glycol, triethylene glycol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Diethylene glycol (DEG) is an organic compound with the formula (HOCH2CH2)2O. It is a colorless, practically odorless, and hygroscopic liquid with a sweetish taste. It is a four carbon dimer of ethylene glycol. It is miscible in water, alcohol, ether, acetone, and ethylene glycol.[3] DEG is a widely used solvent.[4] It can be a normal ingredient in various consumer products, and it can be a contaminant. DEG has also been misused to sweeten wine and beer, and to viscosify oral and topical pharmaceutical products. Its use has resulted in many epidemics of poisoning since the early 20th century.[3]

  1. ^ "Diethylene glycol (CHEBI:46807)".
  2. ^ DEG: LD50 for rats
  3. ^ a b Cite error: The named reference Schep was invoked but never defined (see the help page).
  4. ^ Siegfried Rebsdat and Dieter Mayer "Ethylene Glycol" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim.doi:10.1002/14356007.a10_101

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